J. Ollivier, Vichot : La durabilité des bétons. Association technique de l'industrie des liants hydrauliques, 2008.

A. Neville, Chloride attack of reinforced concrete: an overview, Materials and Structures, vol.23, issue.2, pp.63-70, 1995.
DOI : 10.1007/BF02473172

K. Tuutti, Corrosion of steel in concrete Rapport technique, Swedish cement and concrete research institute (CBI), 1982.

C. Alonso, C. Andrade, M. Castellote, and P. Castro, Chloride threshold values to depassivate reinforcing bars embedded in a standardized OPC mortar, Cement and Concrete Research, vol.30, issue.7, pp.1047-1055, 2000.
DOI : 10.1016/S0008-8846(00)00265-9

T. Q. Nguyen, Modélisations physico-chimiques de la pénétration des ions chlorures dans les matériaux cimentaires, Thèse de doctorat, 2007.

C. Gehlen, Schiessl : Probability-based durability design for the western scheldt tunnel, structural concrete, Journal of the fib, vol.2, pp.1-7, 1999.

C. Andrade, C. Alonso, A. Arteaga, and P. Tanner, Methodology based on the electrical resistivity for the calculation of reinforcement service life. L'industria italiana del cemento, pp.330-339, 2001.

V. Baroghel-bouny, C. Andrade, R. Torrent, and K. Scrivener, International Workshop on performance based evaluation and indicators for concrete durability, 2007.

M. Masi, D. Colella, G. Radaelli, and L. Bertolini, Simulation of chloride penetration in cement-based materials, Cement and Concrete Research, vol.27, issue.10, pp.1591-1601, 1997.
DOI : 10.1016/S0008-8846(97)00200-7

J. Bigas, La diffusion des ions chlorures dans les mortiers, Thèse de doctorat, 1994.

L. Y. Li and C. L. , Finite element modelling of chloride removal from concrete by an electrochemical method, Corrosion Science, vol.42, issue.12, pp.2145-2165, 2000.
DOI : 10.1016/S0010-938X(00)00044-5

O. Truc, J. P. Ollivier, and L. O. Nilsson, Multi-species stranport in satured cement based materials, C. Andrade et J. Kropp, ´ editeurs : Second International RILEM Workshop on Testing and Modelling the Chloride Ingress into Concrete, pp.247-259, 2000.

M. Thiery, Modélisation de la carbonatation atmosphérique des matériaux cimentaire, Thèse de doctorat, Ecole Nationale des Ponts et Chaussées, 2005.

L. Nilsson, A. Andersen, T. Luping, and P. Utgenannt, Chloride ingress data from field exposure in a swedish road environment, C. Andrade et J. Kropp, ´ editeurs : Second International RILEM Workshop on Testing and Modelling the Chloride Ingress into Concrete, pp.69-83, 2000.

R. Duval, La durabilité des armatures et du béton d'enrobage. La durabilité des bétons, 1992.

V. Baroghel-bouny, B. Capra, and S. Laurens, La durabilité des bétons, Presses de l'´ ecole nationale des Ponts et Chaussées (ENPC), pp.303-385, 2008.

A. V. Saetta, R. V. Scotta, and R. V. Vitaliani, Analysis of chloride diffusion into partially saturated concrete, Materials Journal, 1993.

C. L. Lin and L. S. Lee, A two-ionic-parameter approach for ion activity coefficients of aqueous electrolyte solutions, Fluid Phase Equilibria, vol.205, issue.1, pp.69-88, 2003.
DOI : 10.1016/S0378-3812(02)00275-3

V. S. Ramachandran, R. C. Seeley, and G. M. , Polomark : Free and combined chloride in hydrating cement and cement compounds, Materials and Structures, vol.19, pp.285-289, 1984.

L. Tang and L. O. Nilsson, Chloride binding capacity and binding isotherms of opc pastes and mortar, Cement and Concrete Research, vol.23, pp.247-253, 1993.

L. Nilsson, L. Tang, J. Marchand, J. J. Beaudoin, R. D. Hooton et al., Interaction and its effect on substance transport in concrete Materials science of concrete, Special volume : Ion and mass transport in cement-based materials, pp.155-180, 2001.

M. Castellote, C. Andrade, C. Alonso, E. Samson, and J. Marchand, Chloride-binding isotherms in concrete submitted to non-steady-state migration experiments, Proc. 2nd Int. RILEM symp. on Advances in concrete through science and engineering, pp.1799-1806, 1999.
DOI : 10.1016/S0008-8846(99)00173-8

C. Arya, N. R. Buenfeld, and J. B. Newman, Factors influencing chloride-binding in concrete, Cement and Concrete Research, vol.20, issue.2, pp.291-300, 1990.
DOI : 10.1016/0008-8846(90)90083-A

E. M. Theissing, T. M. De-larr, and G. De-wind, The combining of sodium chloride and calcium chloride by the hardened portland cement compounds C3S, C3A and C4AF, 8th Int. Symposium on Chemistry of Cement, pp.823-828, 1986.

A. Suryavanshi and J. D. , Mechanism of Friedel's salt formation in cements rich in tri-calcium aluminate, Cement and Concrete Research, vol.26, issue.5, pp.717-727, 1996.
DOI : 10.1016/S0008-8846(96)85009-5

J. J. Beaudoin, V. S. Ramachandran, and R. F. Feldman, Interaction of chloride and C???S???H, Cement and Concrete Research, vol.20, issue.6, pp.875-883, 1990.
DOI : 10.1016/0008-8846(90)90049-4

G. Arliguie, Hornain : GranDuBé -Grandeurs associéesassociéesà la Durabilité des Béton, 2007.

V. Baroghel-bouny, X. Wang, M. Thiéry, M. Saillio, and F. Barberon, Prediction of chloride binding isotherms of cementitious materials by analytical model or numerical inverse analysis, Cement and Concrete Research, vol.42, issue.9
DOI : 10.1016/j.cemconres.2012.05.008

URL : https://hal.archives-ouvertes.fr/hal-01295062

T. Zhang and E. O. Gjorv, Effect of ionic interaction in migration testing of chloride diffusivity in concrete, Cement and Concrete Research, vol.25, issue.7, pp.1535-1542, 1995.
DOI : 10.1016/0008-8846(95)00147-5

J. O. Bockris and A. K. Reddy, Modern Aspects of Electrochemistry, 1997.

V. S. Ramachandran, R. C. Seeley, and G. M. Polomark, Possible states of chloride in the hydration of tricalcium silicate in the presence of calcium chloride, Mat??riaux et Constructions, vol.17, issue.6, pp.3-12, 1971.
DOI : 10.1007/BF02473926

H. Justnes, A review of chloride binding in cementitious systems, Nordic Concrete Research, vol.21, pp.1-6, 1998.

X. Wang, M. Thiéry, and V. Baroghel-bouny, Determination of binding isotherms by inverse analysis and prediction of the influence of hydroxyl on chloride penetration, 3rd Int. PhD Workshop on Modelling the Durability of reinforced Concrete, 2009.

F. M. Lea, The Chemistry of Cement and Concrete, 1970.

V. Baroghel-bouny, X. Wang, and M. Thiéry, Prediction of chloride binding isotherms by analytical model or numerical inverse analysis, 2nd International Symposium on Service Life Design for Infrastructures, pp.513-526, 2010.
URL : https://hal.archives-ouvertes.fr/hal-01295062

M. Collepardi, A. Marcialis, and R. Turriziani, The kinetics of chloride ions penetration in concrete (in italian), Il Cemento, issue.67, pp.157-164, 1970.

C. Andrade, Calculation of chloride diffusion coefficients in concrete from ionic migration measurements, Cement and Concrete Research, vol.23, issue.3, pp.724-742, 1993.
DOI : 10.1016/0008-8846(93)90023-3

L. Tang and L. O. , Nilsson : A numerical method for prediction of chloride penetration into concrete structures, NATO/RILEM Workshop on the Modeling of Microstructure and its Potential for Studying Transport Properties and Durability, 1994.

L. Nilsson, E. Poulsen, H. E. Sorensen, P. Sandberg, and O. Klinghoer, Chloride Penetra tion Into Concrete-State of the Art. The Danish Road Directorale, 1996.

. Duracrete, General Guidelines for Durability Design and Redesign The European Union ? Brite EuRam III, Research Project No. BE95-1347 : " Probabilistic Performance Based Durability Design of Concrete Structures, 2000.

Y. P. Xi and Z. P. , Modeling Chloride Penetration in Saturated Concrete, Journal of Materials in Civil Engineering, vol.11, issue.1, pp.58-64, 1999.
DOI : 10.1061/(ASCE)0899-1561(1999)11:1(58)

L. Tang, Chloride Transport in Concrete -Measurement and Prediction, PhD thesis, Departement of building materials, Thèse de doctorat, Departement of building materials, 1996.

A. Khitab, Modélisation des transferts ioniques dans les milieux poreux saturés : applicationàapplicationà la pénétration des chloruresàchloruresà travers les matériaux cimentaires, Thèse de doctorat, Institut National des science appliquées de Toulouse, 2005.

J. Marchand, Modeling the behavior of unsaturated cement systems exposed to aggressive chemical environments, Materials and Structures, vol.27, issue.1, pp.195-200, 2000.
DOI : 10.1007/BF02480588

J. Marchand, E. Samson, Y. Maltais, R. J. Lee, and S. Sahu, Predicting the performance of concrete structures exposed to chemically aggressive environment???Field validation, Materials and Structures, vol.23, issue.10, pp.623-631, 2002.
DOI : 10.1007/BF02480355

G. T. Yeh and V. S. Tripatri, A critical evaluation of recent developments in hydrogeochemical transport models of reactive multichemical components, Water Resources Research, vol.67, issue.44, pp.93-108, 1989.
DOI : 10.1029/WR025i001p00093

M. A. Guillem-de-vera, E. Climent, C. Viqueira, C. Antón, and . Andrade, A test method for measuring chloride diffusion coefficients through partially saturated concrete. Part II: The instantaneous plane source diffusion case with chloride binding consideration, Cement and Concrete Research, vol.37, issue.5, pp.714-724, 2007.
DOI : 10.1016/j.cemconres.2007.01.008

G. Lin, Y. Liu, and Z. , Xiang : Numerical modeling for predicting service life of reinforced concrete structures exposed to chloride environments. Cement and Concrete Composites, pp.571-579, 2010.

J. F. Da¨?anda¨?an and N. Madjoudj, Diffusion de sels dans les matériaux humides analyse des processus couplés etétudeetétude expérimentale. Revue français de génie civil, pp.331-355, 2001.

O. Amiri, A??tA??t-Mokhtar : Predicting service life of reinforced structures under marine environment : combined effect of diffusion coefficient and chloride binding, Journal for Science and Engineering, issue.1C, pp.3142-52, 2006.

H. Sleiman and O. Amiri, Chloride transport in unsaturated cement-based materials, European Journal of Environmental and Civil Engineering, vol.5, issue.25, pp.489-499, 2009.
DOI : 10.1016/1065-7355(94)90033-7

URL : https://hal.archives-ouvertes.fr/hal-00535601

O. Francy, Modélisation de la pénétration des ions chlorures dans les mortiers partiellement satures en eau, Thèse de doctorat, 1998.

E. Samson, J. Marchand, and J. J. Beaudoin, Describing ion diffusion mechanisms in cement-based materials using the homogenization technique, Cement and Concrete Research, vol.29, issue.8, pp.1341-1345, 1999.
DOI : 10.1016/S0008-8846(99)00101-5

T. Q. Nguyen, V. Baroghel-bouny, and P. , Prediction of chloride ingress into saturated concrete on the basis of a multi-species model by numerical calculations, Computers and Concrete, vol.3, issue.6, pp.401-422, 2006.
DOI : 10.12989/cac.2006.3.6.401

URL : https://hal.archives-ouvertes.fr/hal-00906116

V. Baroghel-bouny and M. Thiéry, Modelling of isothermal coupled moisture???ion transport in cementitious materials, Cement and Concrete Research, vol.41, issue.8, pp.828-841, 2011.
DOI : 10.1016/j.cemconres.2011.04.001

D. Bentz and S. Rémond, Incorporation of fly ash into a 3-d cement hydration model. Rapport technique, National institute of Standands and Technoloty, 1997.

A. Fraay, J. Bijen, and Y. De-hann, The reaction of fly ash in concrete a critical examination, Cement and Concrete Research, vol.19, issue.2, pp.235-246, 1989.
DOI : 10.1016/0008-8846(89)90088-4

K. Wesche, Fly Ash in Concrete : Properties and Performance, 1991.

V. Papadakis, Effect of fly ash on Portland cement systems, Cement and Concrete Research, vol.29, issue.11, pp.1727-1736, 1999.
DOI : 10.1016/S0008-8846(99)00153-2

M. D. Nguyen, Modélisation des couplages entre hydratation et dessiccation des matériaux cimentairè a l'issue du décoffrage -Etude de la dégradation des propriétés de transfert, Thèse de doctorat, Ecole National des Ponts et Chaussées, 2009.

S. Q. Li and D. M. Roy, Investigation of relations between porosity, pore structure, and C1??? diffusion of fly ash and blended cement pastes, Cement and Concrete Research, vol.16, issue.5, pp.749-759, 1986.
DOI : 10.1016/0008-8846(86)90049-9

V. Papadakis, Supplementary cementing materials in concrete, Cement and Concrete Research, vol.32, issue.10, pp.1525-1532, 2002.
DOI : 10.1016/S0008-8846(02)00827-X

P. Chindaprasirt, C. Chotithanorm, H. T. Cao, and V. Sirivivatnanon, Influence of fly ash fineness on the chloride penetration of concrete, Construction and Building Materials, vol.21, issue.2, pp.356-361, 2007.
DOI : 10.1016/j.conbuildmat.2005.08.010

F. G. Buttler, Effect of reaction between pulverized-fuel ash and calcium hydroxide on concrete properties ´ editeur : Effects of fly-ash incorporation in cement and concrete, Proceedings symposium annual meeting, pp.155-164, 1981.

. American-concrete-institute and M. Detroit, Ground granulated blastfurnace slag as a cimentitious constituent in concrete, ACI Manulal of Concrete Practice, PartI : Materials and General Properties of concrete, 1994.

W. Chen and H. J. Brouwers, The hydration of slag, part 1: reaction models for alkali-activated slag, Journal of Materials Science, vol.26, issue.2, pp.428-443, 2007.
DOI : 10.1007/s10853-006-0873-2

R. K. Dhir, M. A. El-mohr, and T. Dyer, Chloride binding in GGBS concrete, Cement and Concrete Research, vol.26, issue.12, pp.1767-1773, 1996.
DOI : 10.1016/S0008-8846(96)00180-9

A. B. Fraj, Transfert dans les bétons non saturés : influence de laitiers et de l'endommagement mécanique, Thèse de doctorat, 2009.

B. Kolani, Comportement au jeunê age des structures en béton arméarméà base de liants composés aux laitiers, Thèse de doctorat

A. Meyer, Investigations on the carbonation of concrete The Cement Association of Japan, 5th International Symposium on Cement Chemistry, pp.394-401, 1968.

Z. Sauman, Carbonization of porous concrete and its main binding components, Cement and Concrete Research, vol.1, issue.6, pp.645-662, 1971.
DOI : 10.1016/0008-8846(71)90019-6

G. Groves, D. Rodway, and I. Richardson, The carbonation of hardened cement pastes Advances in Cement Research, pp.117-125, 1990.

V. Papadakis and C. , Experimental investigation and mathematical modeling of the concrete carbonation problem, Chemical Engineering Science, vol.46, issue.5-6, pp.1333-1338, 1991.
DOI : 10.1016/0009-2509(91)85060-B

B. Bary and A. Sellier, Coupled moisture-carbon dioxide-calcium transfer model for carbonation of concrete Hyvert : Application d'une approche probabilistè a la durabilité des produits préfabriqués en béton, Thèse de doctorat, pp.1859-1872, 2004.

E. Drouet, Impact de la température sur la carbonatation des matériaux cimentaires : prise en compte des transferts hydriques, Thèse de doctorat, ´ Ecole normale supérieure de Cachan, 2010.

D. Conciatori and H. Sadouki, Capillary suction and diffusion model for chloride ingress into concrete, Cement and Concrete Research, vol.38, issue.12, pp.1401-1408, 2008.
DOI : 10.1016/j.cemconres.2008.06.006

V. T. Ngala and C. L. , Page : Effects of carbonation on pore structure and diffusional properties of hydrated cement pastes, Cement and Concrete Research, vol.12, pp.1248-1254, 1997.

H. W. Song and S. J. , Permeability characteristics of carbonated concrete considering capillary pore structure, Cement and Concrete Research, vol.37, issue.6, pp.909-915, 2007.
DOI : 10.1016/j.cemconres.2007.03.011

Y. F. Houst and F. H. Wittmann, Influence of porosity and water content on the diffusivity of CO2 and O2 through hydrated cement paste, Cement and Concrete Research, vol.24, issue.6, pp.1165-1176, 1994.
DOI : 10.1016/0008-8846(94)90040-X

G. Groves, A. Brough, I. Richardson, and C. Dobson, Progressive Changes in the Structure of Hardened C3S Cement Pastes due to Carbonation, Journal of the American Ceramic Society, vol.2, issue.7, pp.2891-2896, 1991.
DOI : 10.1111/j.1151-2916.1991.tb06859.x

G. Villan, Thiery : Impact of carbonation on microstructure and transport properties of concrete, Proceedings of 10th Conference on Durability of Building Materials and Components, pp.1-8, 2005.

L. D. Ceukelaire and D. V. Nieuwenburg, Accelerated carbonation of a blast-furnace cement concrete. Cement and Concrete Ressearch, pp.442-452, 1993.

S. Diamond, Mercury porosimetry, Cement and Concrete Research, vol.30, issue.10, pp.1517-1525, 2000.
DOI : 10.1016/S0008-8846(00)00370-7

D. Gaspar-tedar, T. Vasquez-moreno, and M. , Nunoz-Plaza : Action du CO2 sur le ciment portland hydraté dans des conditions normales, RILEM International Symposium on Carbonation of Concrete. RILEM, 1976.

M. Daimon, T. Akiba, and R. Kondo, Through Pore Size Distribution and Kinetics of the Carbonation Reaction of Portland Cement Mortars, Journal of the American Ceramic Society, vol.33, issue.2, pp.423-428, 1971.
DOI : 10.1111/j.1151-2916.1971.tb12379.x

A. K. Suryavanshi, R. Narayan, and . Swamy, Stability of Friedel's salt in carbonated concrete structural elements, Cement and Concrete Research, vol.26, issue.5, pp.729-741, 1996.
DOI : 10.1016/S0008-8846(96)85010-1

L. Tang, Concentration dependence of diffusion and migration of chloride ions, Cement and Concrete Research, vol.29, issue.9, pp.1469-1474, 1999.
DOI : 10.1016/S0008-8846(99)00120-9

R. C. Weast, M. J. Astle, and W. H. Beyer, CRC Handbook of chemistry and physics, 1986.

L. Tang, Resistance of concrete to chloride ingress. From laboratory tests to infield performance. Chlortest, 2006.

L. Y. Li and C. L. , Modelling of electrochemical chloride extraction from concrete: Influence of ionic activity coefficients, Computational Materials Science, vol.9, issue.3-4, pp.303-308, 1998.
DOI : 10.1016/S0927-0256(97)00152-3

C. Moyne and M. A. , Electro-chemo-mechanical couplings in swelling clays derived from a micro/macro-homogenization procedure, International Journal of Solids and Structures, vol.39, issue.25, pp.6159-6190, 2002.
DOI : 10.1016/S0020-7683(02)00461-4

H. F. Taylor, A method for predicting alkali ion concentration in cement pore solution Advances in Cement Research, pp.5-16, 1987.

H. J. Brouwers and R. J. , Alkali concentrations of pore solution in hydrating OPC, Cement and Concrete Research, vol.33, issue.2, pp.191-196, 2003.
DOI : 10.1016/S0008-8846(02)01022-0

H. W. Pollitt and A. W. Brown, The distribution of alkalis in portland cement clinker, 5th International Symposium on the Chemistry of Cement, pp.322-333, 1969.

M. D. Nguyen, M. Thiery, and P. Belin, A Model for Hydration-Drying Interactions in the Concrete Cover, Third International Conference on Coupled, 2008.
DOI : 10.1002/9781118623565.ch57

W. Chen and H. J. Brouwers, Alkali binding in hydrated portland cement paste. Cement and Concrete Ressearch, pp.716-722, 2010.

S. Y. Hong and F. P. Glasser, Alkali binding in cement pastes, Cement and Concrete Research, vol.29, issue.12, pp.1893-1903, 1999.
DOI : 10.1016/S0008-8846(99)00187-8

L. J. Klinkenberg, The permeability of porous media to liquids and gases, drilling and production practice American Petroleum Institute, 1941.

M. Mainguy, Modèles de diffusion non-linéaires en milieux poreux Applicationàcationà la dissolution et au séchage des matériaux cimentaires, Thèse de doctorat, Ecole Nationale des Ponts et Chaussées, 1999.

A. J. Katz and A. H. Thompson, Quantitative prediction of permeability in porous rock, Physical Review B, vol.34, issue.11, pp.8179-8181, 1986.
DOI : 10.1103/PhysRevB.34.8179

D. A. De-vries and A. J. Kruger, On the value of the diffusion coefficient of water vapor in air, Proc. Of Colloque Int Phénomènes de Transport Avec Changement de Phase Dans Les Milieux Poreux Ou Collo¨?dauxCollo¨?daux, pp.61-72, 1966.

R. J. Millington and R. C. Shearer, DIFFUSION IN AGGREGATED POROUS MEDIA, Soil Science, vol.3, issue.6, pp.372-378, 1970.
DOI : 10.1097/00010694-197103060-00007

V. Papadakis and C. Vayenas, Fardis : Physical and chemical characteristics affecting the durability of concrete, ACI Materials Journal, vol.88, pp.186-196, 1991.

A. Buchwald, Determination of the ion diffusion coefficient in moisture and salt loaded masonry materials by impedance spectroscopy, 3rd International PhD. Symposium, pp.475-482, 2000.

Y. Mualem, A new model for predicting the hydraulic conductivity of unsaturated porous media, Water Resources Research, vol.12, issue.4, pp.513-522, 1976.
DOI : 10.1029/WR012i003p00513

G. Villain, V. Baroghel-bouny, C. Kounkou, and C. Hua, Mesure de la perméabilité aux gaz en fonction du taux de saturation des bétons. Revue française de génie civil, pp.2-3251, 2001.

N. Monlouis-bonnaire and J. Verdier, Prediction of the relative permeability to gas flow of cement-based materials, Cement and Concrete Research, vol.34, issue.5, pp.737-744, 2004.
DOI : 10.1016/S0008-8846(03)00071-1

K. S. Pitzer, Electrolyte theory - improvements since Debye and Hueckel, Accounts of Chemical Research, vol.10, issue.10, pp.268-277, 1973.
DOI : 10.1021/ar50118a004

H. Lin and L. Lee, Estimations of activity coefficients of constituent ions in aqueous electrolyte solutions with the two-ionic-parameter approach, Fluid Phase Equilibria, vol.237, issue.1-2, pp.1-8, 2005.
DOI : 10.1016/j.fluid.2005.08.005

R. Eymard, T. Gallouet, and R. , Herbin : Handbook of Numerical Analysis, volume The Finite Volume Method, 2000.

J. A. Nelder and R. Mead, A simplex for function minimization, Computer Jounal, pp.308-313, 1965.

T. G. Kolda, R. M. Lewis, and V. Torczon, Optimization by Direct Search: New Perspectives on Some Classical and Modern Methods, SIAM Review, vol.45, issue.3, pp.385-482, 2003.
DOI : 10.1137/S003614450242889

O. Coussy, V. Baroghel-bouny, P. Dangla, and M. Mainguy, Evaluation de la perméabilitéperméabilitéà l'eau liquide des bétonsbétons`bétonsà partir de leur perte de masse durant le séchage. Revue Français de Génie Civil, pp.269-284, 2000.
DOI : 10.1080/12795119.2001.9692307

F. American and . Testing, Standard Test Method for Field Measurement of Soil Resistivity Using Wenner Four-Electrode Method, 1984.

O. Sengul and O. E. Gjorv, Effect of embedded steel on electrical resistivity measurements on concrete structures, ACI Materials Journal, vol.106, pp.11-18, 2009.

C. Andrade, C. Alonso, and S. Goni, Possibilities for electrical resistivity to universally characterise mass transport processes in concrete, Concrete 2000 : Economic and Durable Construction Through Excellence, pp.1639-1652, 1993.

W. Morris, E. I. Moreno, and A. A. , Practical evaluation of resistivity of concrete in test cylinders using a Wenner array probe, Cement and Concrete Research, vol.26, issue.12, pp.1779-1787, 1996.
DOI : 10.1016/S0008-8846(96)00175-5

D. Baweja, H. Roper, and V. , Sirivivatnanon : Specifications of concrete for marine environments : A fresh approach, ACI Materials Journal, vol.96, pp.462-470, 1999.

A. S. El-dieb and R. D. Hooton, Evaluation of the Katz-Thompson model for estimating the water permeability of cement-based materials from mercury intrusion porosimetry data, Cement and Concrete Research, vol.24, issue.3, pp.443-455, 1994.
DOI : 10.1016/0008-8846(94)90131-7

P. Tumidajski and B. Lin, On the Validity of the Katz-Thompson Equation for Permeabilities in Concrete 11Communicated by C.M. Hansson., Cement and Concrete Research, vol.28, issue.5, pp.643-647, 1998.
DOI : 10.1016/S0008-8846(98)00032-5

M. Thiery, G. Villain, and W. Jafaar, Estimation de la perméabilité des matériaux cimentaires par porosimétrie au mercure, In Bulletin du GFHN, vol.46, pp.139-144, 2003.

V. Baroghel-bouny, P. Belin, M. Castellote, N. Rafa¨?rafa¨?, P. Rougeau et al., Yssorche-Cubaynes : Which toolkit for durability evaluation as regards chloride ingress into concrete ? Part I : Comparison between various methods for assessing the chloride diffusion coefficient of concrete in saturated conditions, Third International RILEM Workshop on Testing and Modelling Chloride Ingress into Concrete, pp.105-136, 2002.

V. Baroghel-bouny, P. Belin, M. Maultzsch, and D. Henry, AgNO3 spray tests: advantages, weaknesses, and various applications to quantify chloride ingress into concrete. Part 1: Non-steady-state diffusion tests and exposure to natural conditions, Materials and Structures, vol.34, issue.7, pp.759-781, 2007.
DOI : 10.1617/s11527-007-9233-1

URL : https://hal.archives-ouvertes.fr/hal-00349024

T. Chaussadent, AFREM test procedures concerning chlorides in concrete: Extraction and titration methods, Materials and Structures, vol.20, issue.4, pp.230-234, 1999.
DOI : 10.1007/BF02481520

M. Castellote, C. Andrade, and C. Alonso, Measurement of the steady and non-steady-state chloride diffusion coefficients in a migration test by means of monitoring the conductivity in the anolyte chamber. comparison with natural diffusion tests. Cement and Concrete Ressearch, pp.1411-1420, 2001.

V. Baroghel-bouny, K. Kinomura, M. Thiery, and S. Moscardelli, Easy assessment of durability indicators for service life prediction or quality control of concretes with high volumes of supplementary cementitious materials, Cement and Concrete Composites, pp.832-847, 2011.
DOI : 10.1016/j.cemconcomp.2011.04.007

URL : https://hal.archives-ouvertes.fr/hal-00913221

V. Baroghel-bouny, J. Gawsewitch, P. Belin, K. Ounoughi, S. Arnaud et al., Ageing of concrete in natural environments : An experiment for the 21st century. IV. Results on cores extracted from field-exposed test specimens of various sites as part of the first measurement sequence, Bulletin Laboratoire des Ponts et Chaussées, issue.249, pp.49-100, 2004.

V. Baroghel-bouny and T. , Chaussadent : Caractéristique microstructurales et propriétés relativesàrelativesà la durabilité des bétons, 2002.

K. Hong and R. D. Hooton, Effects of cyclic chloride exposure on penetration of concrete cover, Cement and Concrete Research, vol.29, issue.9, pp.1379-1386, 1999.
DOI : 10.1016/S0008-8846(99)00073-3

K. Scrivener, The percolation of pore space in the cement paste/aggregate interfacial zone of concrete, Cement and Concrete Research, vol.26, issue.1, pp.35-40, 1996.
DOI : 10.1016/0008-8846(95)00185-9

M. Thiéry, P. Faure, A. Morandeau, G. Platret, J. F. Bouteloup et al., Effect of carbonation on the microstructure and the moisture properties of cement-based materials, International Conference on Durability of Building Materials and Components, 2011.

V. Baroghel-bouny and M. , Thiéry : Modelling of coupled moisture-ions transport in concrete, Symposium on concrete modelling CONMOD '10, pp.22-25, 2010.

H. Ranaivomanana, Transferts dans les milieux poreux réactifs non saturés : applicationàapplicationà la cicatrisation de fissure dans les matériaux cimentaires par carbonatation, Thèse de doctorat, 2010.

H. Ranaivomanana, J. Verdier, A. Sellier, and X. Bourbon, Toward a better comprehension and modeling of hysteresis cycles in the water sorption???desorption process for cement based materials, Cement and Concrete Research, vol.41, issue.8, pp.817-827, 2011.
DOI : 10.1016/j.cemconres.2011.03.012

URL : https://hal.archives-ouvertes.fr/hal-01098091

F. Deby, M. Carcassès, and A. Sellier, Probabilistic approach for durability design of reinforced concrete in marine environment, Cement and Concrete Research, vol.39, issue.5, pp.466-471, 2009.
DOI : 10.1016/j.cemconres.2009.03.003

J. Mai-nhu, A. Sellier, F. Duprat, P. Rougeau, B. Capraand et al., Probabilistic approach for durable design of concrete cover: application to carbonation, European Journal of Environmental and Civil Engineering, vol.32, issue.3-4, 2012.
DOI : 10.1080/19648189.2012.667705

V. Baroghel-bouny, M. Thiéry, and X. Wang, Performance-based assessment of durability and prediction of rc structure service life by deterministic and probabilistic physical models

A. Djerbi, S. Bonnet, and A. Khelidj, Baroghel-bouny : Influence of traversing crack on chloride diffusion into concrete, Cement and Concrete Research, vol.8, pp.877-883, 2008.

V. Picandet, A. Khelidj, and H. Bellegou, Crack effects on gas and water permeability of concretes, Cement and Concrete Research, vol.39, issue.6, pp.537-547, 2009.
DOI : 10.1016/j.cemconres.2009.03.009

URL : https://hal.archives-ouvertes.fr/hal-00494399

K. Erdogdua, Effects of fly ash particle size on strength of portland cement fly ash mortars, Cement and Concrete Research, vol.28, issue.9, pp.1217-1222, 1998.
DOI : 10.1016/S0008-8846(98)00116-1

C. Gauthier, Optimisation des mesures de rayonnement : application aux mesures de masse volumique par gammadensimétrie. Rapport technique, Laboratoire Central des Ponts et Chaussées, 1968.

V. Baroghel-bouny, M. Mainguy, T. Lassabatere, and O. Coussy, Characterization and identification of equilibrium and transfer moisture properties for ordinary and high-performance cementitious materials, Cement and Concrete Research, vol.29, issue.8, pp.1225-1238, 1999.
DOI : 10.1016/S0008-8846(99)00102-7

URL : https://hal.archives-ouvertes.fr/hal-00586623

G. Villain and P. Roussel, Mode opératoire et consignes : essais sur le banc de gammadensimétrie, Laboratoire Central des Ponts et Chaussées, 2002.

A. De-nelder-mead and B. , 1 Mise en oeuvre de l'algorithme de Nelder- Mead Pour lancer le processus de l'optimisation avec l'algorithme de Nelder-Mead, le premier sommet du simplex initial