. En-présence-d-'albumine, usure est similaire quel que soit le pH mais l'adsorption de l'albumine dans la zone d'usure n'est pas la même On peut remarquer que plus le pH diminue, plus la quantité d'albumine est importante. Si on observe la zone d'usure à plus fort grandissement (Figure 3.38), on peut voir l'agglomération de l'albumine et de débris pour les conditions de pH 4 et 2. Dans les deux cas, on peut voir les rayures causées par le frottement. L'albumine ne semble pas s'adsorber directement à la surface du 316L. La dégradation est d'abord mécanique (rayures) puis l'albumine s'adsorberait à la surface

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L. 'usure-du and P. , Cependant, elle ne dépend pas non plus de l'énergie dissipée cumulée : il est possible que seule une partie de l'E dc serve à user le PMMA et que l'autre, fonction de la force ionique, joue un rôle dans l'usure du 316L. En présence d'albumine, le volume d'usure total du 316L ainsi que le volume d'usure corrosive sont largement diminués. Cela confirme le rôle d'inhibiteur de corrosion de l'albumine. À l'inverse, le volume d'usure du PMMA augmente en présence d'albumine : la mise en place d'un régime de lubrification mixte, i.e. l'albumine adsorbée à la surface provoque un contact entre les aspérités, 2007.

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. Dans-notre-cas, nous avons montré que 80 % des particules ont un diamètre inférieur à 100 nm. Il est alors possible que des particules d'un diamètre équivalent soient générées in vivo

. La-forme-de-la-trace, au cours de l'essai, peuvent laisser supposer une diminution du pH dans la trace d'usure et plus particulièrement au creux du " W " , ainsi que la mise en place d'un gradient de pH entre la zone d'usure et la zone extérieure au contact. Cependant, la mesure du pH local, dans la zone d'usure, est difficile à mettre en place. C'est pourquoi le pH global de la solution est fixé. Les mesures de courant, d'énergie dissipée et de volume d'usure ont permis de mettre en place une hypothèse

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