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1. Hz, 18 (dd, J = 15.6 Hz

1. Hz, 4.73 (t, J = 9.9 Hz, pp.73-76

1. Hz, 21 (d, J = 9, Hz, 1H, NH), 3.04 (dd, J = 13.8 Hz, J = 9.0 Hz, 1H, H4), 2.43 (s, 3H, Me), p.35

2. Hz, 2. , and H. +. Nh, 50 (br. s, 1H, OH, dia2), 4.64-4.84 (m, 3H, H7 + H12), 4.28 (q, ), 2.48-2.55 (m, 1H, H3 dia2), pp.9259-9264

9. Chiralcel, A. , and H. , flow rate = 1.0 mL/min, 254 nm) minor isomer : t R = 15.84 min; major isomer : t R = 66, p.1

1. Hz, 80 (br. s, 1H, NH), 3.77 (s, 3H, OMe), 3.38-3, H2), 2.56-2.65 (m, 1H, H3a), 2.29-2.44 (m, 1H, H3), pp.66-67

9. Chiralcel, A. , and H. , flow rate = 1.0 mL/min, 254 nm) minor isomer : t R = 17.30 min; major isomer : t R = 55, p.1

9. Chiralcel, A. , and H. , flow rate = 1.0 mL/min, 254 nm) minor isomer : t R = 17.95 min; major isomer : t R = 53

J. =. Hz and . 1h, 86 (s, 3H, OMe), 3.76 (s, 3H, OMe), 5.1 Hz, 1H38-3.49 (m, 2H, H2).70 (m, 1H, H3a), pp.61-231

1. Hz and H. , 40 (dd, Hz, J = 1.8 Hz, 1H, H9'), pp.59-60

J. =. Hz, 76 (s, 3H, OMe), 5.1 Hz, 1H79 (d, J = 2.7 Hz, 1H, H4) 2H, H2), 2.79-2.88 (m, 1H, H3a), pp.46-49