B. Aastrup, T. Wadsak, M. Schreiner, M. Leygraf, and C. , Experimental in situ studies of copper exposed to humidified air, Corrosion Science, vol.42, issue.6, pp.957-967, 2000.
DOI : 10.1016/S0010-938X(99)00125-0

A. , M. Araújo, and L. V. De-levi-m, Voltammetric studies on copper deposition/dissolution reactions in aqueous chloride solutions, Minerals Engineering, vol.8, issue.12, pp.1467-1475, 1995.

A. _________________, Limitation to the Mixed Potential Concept of Metal Corrosion Copper in Oxygenated Sulfuric Acid Solutions, Electrochimica Acta, vol.49, pp.3283-3292, 2004.

A. , I. V. Vienna, and E. C. Atmosférica, Disponível em http, 2006.

A. , I. V. Bernard, M. , S. I. Deslouis, C. De-melo et al., Ac-impedance and Raman spectroscopy study of the electrochemical behaviour of pure aluminium in citric acid media, Estudo comparativo de ensaios acelerados para simulação da corrosão atmosférica. 2000. 85f. Dissertação (Mestrado) ? Instituto de Pesquisa Energéticas Nucleares, pp.1871-1878, 2000.

B. , R. Hukovic, M. M. Jukic, and A. , A Study of Copper Passivity by Electrochemical Impedance Spectroscopy, Journal of the Electrochemical Society, vol.148, issue.4, pp.146-151, 2001.

B. , A. L. Griess-jr, and J. C. , The Anodic Dissolution of Copper in Flowing Sodium Chloride Solutions Between 25° and 1 75°C, Journal of Electrochemical Society, vol.120, issue.4, pp.459-465, 1973.

B. , W. A. El-egamy, S. S. El-azab, and A. S. , The electrochemical behavior of leaded brass in neutral Cl and SO4 media, Corrosion Science, vol.37, pp.12-1969, 1995.

B. , O. E. Mattos, O. R. Pébère, and N. , Mass-transport study for the electrodissolution of copper in 1M hydrochloric acid solution by impedance, Journal of the Electrochemical Society, vol.140, issue.10, pp.2825-2832, 1993.

B. , A. J. Faulkner, and L. R. , Electrochemical methods fundamentals and applications. 2, 2001.

J. G. Becerra, R. S. Salvareza, and A. J. Arvia, Electrochemical behaviour of copper in aqueous solution containing potassium ethylxanthate, Journal of Applied Electrochemistry, vol.30, issue.4, pp.779-788, 1987.
DOI : 10.1007/BF01007815

B. , N. Cavanaugh, M. K. Buchheit, and R. G. , Electrochemical behavior and localized corrosion associated with Al 7 Cu 2 Fe particles in aluminum alloy 7075-T651, Corrosion Science, vol.48, issue.12, pp.4202-4215, 2006.

B. , N. Padgett, B. N. Buchheit, and R. G. , Limitations in microelectrochemical capillary cell testing and transformation of electrochemical transients for acquisition of microcell impedance data, Electrochimica Acta, vol.50, pp.16-17, 2005.

B. , C. ;. Pebere, N. ;. Tribollet, B. Vivier, and V. , Galvanic coupling between copper and aluminium in a thin-layer cell, Corrosion Science, vol.52, pp.991-995, 2010.

P. J. Boden and P. J. Boden, Corrosion of Cu and Cu-base alloys under conditions of boiling heat transfer???I. Corrosion of Cu, Corrosion Science, vol.11, issue.6, pp.353-362363, 1971.
DOI : 10.1016/S0010-938X(71)80118-X

C. , G. P. Crespo, M. A. Rosales, and B. M. , Comparative study of patinas formed on statuary alloys by means of electrochemical and surface analysis techniques, Corrosion Science, vol.46, issue.4, pp.929-953, 2004.

C. , B. E. Bockris, and J. O. , On the calculation of potential energy profile diagrams for processes in electrolytic metal deposition, Electrochimica Acta, vol.3, issue.4, pp.340-366, 1961.

C. , G. G. Barcia, O. E. Mattos, and O. , Copper electrodissolution mechanism in a 1M sulphate medium, Electrochimica Acta, vol.38, pp.2-3, 1993.

C. , J. Pardessus, L. Crousier, and J. , Voltammetry study of copper in chloride solution, Electrochimica Acta, vol.33, issue.8, pp.1039-1042, 1988.

D. , J. F. Kelly, and R. G. , The Evolution of the Adsorbed Solution Layer during Atmospheric Corrosion and Its Effects on the Corrosion Rate of, Copper Journal of the Electrochemical Society, vol.140, pp.1890-1897, 1993.

D. La-fuente, D. Simancas, J. Morcillo, and M. , Morphological study of 16-year patinas formed on copper in a wide range of atmospheric exposures, Corrosion Science, vol.50, issue.1
DOI : 10.1016/j.corsci.2007.05.030

D. Levie and R. , Electrochemical response of porous and rough electrodes

D. , C. Mattos, O. R. Musiani, M. M. Tribollet, and B. , Comments on mechanisms of copper electrodissolution in chloride media, Electrochimica Acta, vol.38, issue.18, pp.2781-2783, 1993.

D. , D. Lantelme, F. Chemia, and M. , Surface processes: Effect of ohmic polarization on potentiodynamic V/I curves, Electrochimica Acta, vol.31, issue.10, pp.1235-1245, 1986.

D. , J. Le-canut, J. Le-gorrec, B. Montella, and C. , Copper electrodissolution in 1 M HCl at low current densities. II. Electrochemical impedance spectroscopy study, Electrochimica Acta, vol.43, pp.16-17, 1998.

D. , C. F. Fu, A. Q. Li, X. G. Cheng, and Y. , Localized EIS characterization of corrosion of steel at coating defect under cathodic protection, Electrochimica Acta, vol.54, pp.628-633, 2008.

D. , E. Lavie, P. Dalard, F. Caire, J. Szunerits et al., Corrosion of galvanised steel under an electrolytic drop, Corrosion Science, vol.49, issue.2, pp.910-919, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00333717

E. , C. I. Salvareza, R. C. Arvia, and A. J. , The influence of halide ions at submonolayer levels on the formation of oxide layer and electrodissolution of copper in neutral solutions, Electrochimica Acta, vol.33, pp.12-1735, 1988.

F. , I. T. Picciochi, R. Mendonça, M. H. Ramos, and A. C. , The atmospheric corrosion of copper at two sites in Portugal: a comparative study, Corrosion Science, vol.46, issue.3, pp.547-561, 2004.

F. , J. Davis, and E. , Metalographic studies of copper patina formed in the atmosphere, Corrosion Science, vol.27, issue.7, pp.659-668, 1987.

F. , I. Huang, V. M. Orazem, M. E. Pébère, N. Tribollet et al., Local electrochemical impedance spectroscopy: considerations about the cell geometry, Electrochimica Acta, vol.53, pp.7386-7395, 2008.

F. , L. Nóvoa, X. R. Pena, G. Vivier, and V. , On the corrosion mechanism of AISI 204Cu stainless steel in chlorinated alkaline media, Corrosion Science, vol.50, issue.11, pp.3205-3212, 2008.

R. , P. Vivier, and V. , Development of a Coupled SECM-EQCM Technique for the Study of Pitting Corrosion on Iron, Journal of the Electrochemical Society, vol.153, pp.68-74, 2006.

G. , B. Denoël, S. Weber, G. Allart, and D. , Analysis of green copper pigments in illuminated manuscripts by micro-Raman spectroscopy Analyst

G. , Y. Tribollet, B. Dagbert, C. Hyspecka, and L. , A Physical Model for Anticorrosion Behavior of Duplex Coatings, Journal of Electrochemical Society, vol.153, issue.5, p.162, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00133262

G. , T. E. Nassau, K. Franey, and J. P. , Copper patinas formed in the atmosphere-I. Introduction, Corrosion Science, vol.27, issue.7, pp.639-657, 1987.

H. , V. Guillaume, J. Terryn, H. Hubin, and . Micro, Raman spectroscopy for the study of corrosion products on copper alloys: setting up of a reference database and studying works of art, Journal of Raman Spectroscopy, vol.35, pp.732-738, 2004.

. Dissertação, Mestrado em Engenharia Química)-Escola Politécnica da, 2004.

J. , J. Orazem, M. E. Pébère, and N. , CPE analysis by local electrochemical impedance spectroscopy, Electrochimica Acta, vol.51, pp.8-9, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00476972

J. , J. B. Krawiec, H. Pébère, N. Vignal, and V. , Comparison of local electrochemical impedance measurements derived from bi-electrode and microcapillary techniques, Electrochimica Acta, vol.54, pp.245775-5781, 2009.

K. , M. Kiyak, T. Sendil, O. Asan, and A. , Electrochemical bahavior of brass in 0, 1M Nacl. Applied Surface Science, vol.193, pp.167-174, 2002.

K. , C. Wallinder, I. O. Heijerick, D. Leygraf, and C. , Runoff rates, chemical speciation and bioavailability of copper released from naturally patinated copper Environmental Pollution, pp.691-700, 2002.

K. , G. Barker, B. D. Walsh, and F. C. , Electrochemical corrosion of unalloyed copper in chloride media ? a critical review, Corrosion Science, vol.46, issue.1, pp.109-135, 2004.

K. , H. Beccu, and K. D. Gutjahr-m, Abschätzung der porenstruktur poröser elektroden aus impedanzmessungen, Electrochimica Acta, vol.21, issue.8, pp.539-543, 1976.

K. , H. A. Conway, and B. E. Klinger, Computer simulation of the kinetic behaviour of surface reactions driven by a linear potential sweep

K. , T. Merl, D. K. Milosev, and I. , Impedance and XPS study of benzotriazole films formed on copper, copper?zinc alloys and zinc in chloride solution, Corrosion Science, vol.50, pp.1987-1997, 2008.

K. , T. Furkovif, H. O. Legat, and A. , Investigation of the corrosion protection of chemically and electrochemically formed patinas on recent bronze, Electrochimica Acta, vol.56, issue.2, pp.722-731, 2010.

K. , A. Wallinder, I. O. Leygraf, and C. , The evolution of outdoor copper patina, Corrosion Science, vol.44, issue.3, pp.425-450, 2002.

K. , H. Vignal, V. Oltra, and R. , Use of the electrochemical microcell technique and the SVET for monitoring pitting corrosion at MnS inclusions, Electrochemistry Communications, vol.6, issue.7, pp.655-660, 2004.

L. , T. F. Fontele, A. P. Pedrotti, J. J. Fornaro, and A. , Composição iônica majoritária de águas de chuva no centro da cidade de São Paulo, Química Nova, vol.27, issue.6, pp.855-861, 2004.

L. , H. P. Nobe, and K. , Kinetic and mechanisms of Cu electrodissolution in chloride media, Journal of the Electrochemical Society, vol.133, issue.10, pp.2035-2043, 1986.

L. , H. J. Linden, M. V. De-wit, and J. H. , Corrosion of aluminium in acidic and neutral solutions, Electrochimica Acta, vol.38, issue.14, pp.1989-1992, 1993.

L. , C. Graedel, and T. , Atmospheric corrosion, 2000.

P. , E. Bell, A. M. Thompson, and S. P. , Simultaneous in situ time resolved SR-XRD and corrosion potential analyses to monitor the corrosion on copper, Electrochemistry Communications, issue.7, pp.1265-1270, 2005.

L. , R. S. In, P. Marcus, and F. Mansfeld, Analytical methods in corrosion science and engineering, Boca Raton, pp.571-601, 2006.

L. , R. E. Frankenlhal, R. P. Siconolfi, J. D. Sinclair, and J. D. , The Effect of Submicron Ammonium Sulfate Particles on the Corrosion of, Copper Journal of the Electrochemical Society, vol.140, 1902.

S. , M. Lobnig, R. E. Jankoski, and C. A. , Mechanism of Atmospheric Corrosion of Copper in the Presence of Submicron Ammonium Sulfate Particles at 300 and 373 K Atmospheric Corrosion of Copper in the Presence of Acid Ammonium Sulfate Particles, Journal of the electrochemical society Journal of the Electrochemical Society, vol.141, issue.145 3, pp.2935-2941, 1994.

B. , H. Van-den, B. Bossche, and J. Deconinck, A new microcell or microreactor for material surface investigations at large current densities, Electrochimica Acta, vol.49, pp.17-18, 2004.

L. , Y. Xu, H. Wang, J. Kong, and X. , Oxygen reduction mechanism on copper in a 0, Electrochimica Acta, vol.54, pp.15-3972, 2009.

Y. Lu, W. Wang, H. Xu, X. Kong, and J. Wang, Copper corrosion and anodic electrodissolution mechanisms in naturally aerated stagnant 0, pp.5-7

L. , Q. Mackay, R. A. Babu, and S. V. , Copper Dissolution in Aqueous Ammonia-Containing Media during Chemical-Mechanical Polishing, Chemistry Maerials, vol.9, issue.10, pp.2101-2106, 1997.

M. , G. Duthil, J. P. Giusti, and A. , The pit morphology on copper in chloride-and sulphate-containing solutions, Corrosion Science, vol.39, issue.1, pp.27-42, 1997.

J. A. Morcillo-m, Interaction of copper and NO 2 : Effect of joint presence of SO 2 , relative humidity and temperature, Journal of Physics and Chemistry of Solids, vol.69, issue.4, pp.895-904, 2008.

T. , H. Stupni?ek-lisac, and E. , Comparative studies of chemical and electrochemical preparation of artificial bronze patinas and their protection by corrosion inhibitor, Electrochimica Acta, vol.54, pp.30-7106, 2009.

G. Vivier, V. Sur, and . Impedances-electrochimiques, Étude Electrochimique de la stabilite d'une patine de cuivre a l'aide de la microelectrode a cavite, In: FORUM, pp.183-192, 2010.

M. , M. M. Aoki, I. V. Vivier, and V. G. De-melo-h, Microeletrodo com cavidade: técnica eletroquímica utilizada para estudo da estabilidade de produtos de corrosão de metais, Revista CPC, issue.10, pp.234-251, 2010.

M. , S. M. Antonijevic, and M. M. , Some aspects of copper corrosion in presence of benzotriazole and chloride ions, Corrosion Science, vol.51, pp.28-34, 2009.

M. , B. Fiaud, C. Hinnen, C. Sutter, and E. M. , A correlation between electrochemical behavior, composition and semiconducting properties of naturally grown oxide films on copper, Corrosion Science, vol.37, issue.12, pp.1903-1918, 1995.

M. , C. Trabanelli, G. Meszaros, and G. , Investigation on copper corrosion behaviour in industrial waters by electrochemical noise analysis, Journal of Applied Electrochemistry, vol.28, issue.9, pp.963-969, 1998.

M. , N. Oltra, R. Vuillemin, B. Néel, and O. , Numerical modelling of the galvanic coupling in aluminium alloys: A discussion on the application of local probe techniques, Corrosion Science, vol.52, issue.1, pp.130-139, 2010.

N. , S. Kaji, T. Shibata, M. Notoya, T. Osakai et al., Which Is Easier to Reduce, Cu[sub 2]O or CuO?, Journal of The Electrochemical Society, vol.154, issue.1, pp.1-6, 2007.
DOI : 10.1149/1.2364837

N. , K. Gallagher, P. K. Miller, A. E. Graedel, and T. , The characterization of patina components by x-ray diffraction and evolved gas analysis, Corrosion Science, vol.27, issue.7, pp.669-684, 1987.

N. , G. B. Jaskula, M. Chorkendorff, I. Larsen, and J. , The initial behaviour of freshly etched copper in moderately acid, aerated chloride solutions, Electrochimica Acta, vol.47, pp.27-4279, 2002.

O. , S. E. Faller, and M. , Environmental effects on materials: the effect of the air pollutants SO, NO, O 3 on the corrosion of copper, zinc and aluminium

O. , R. Maurice, V. Akid, R. Marcus, and P. , Local probe techniques for corrosion research. Woodhead: Cambridge, 2007.

O. , M. E. Pébère, N. Tribollet, and B. , Enhanced Graphical Representation of Electrochemical Impedance Data, Journal of The Electrochemical Society, vol.153, issue.4, pp.129-136, 2006.

P. , C. S. Buchheit, and R. G. , The time?temperature?corrosion susceptibility in a 7050-T7451 friction stir weld, Materials Science and Engineering: A, vol.492, pp.1-2, 2008.

P. , E. Kockelmann, W. Chapon, L. C. Lutterotti, L. Bennet et al., Neutron and X-ray characterisation of the metallurgical properties of a 7th century BC Corinthian-type bronze helmet Nuclear Instruments and Methods in, Physics Research B, vol.239, pp.16-26, 2005.

P. , B. Y. Zelinsky, and A. G. , Numerical simulation of electrode process in Cu, Electrochimica Acta, vol.49, issue.20, pp.3283-3292, 2004.

R. , K. Keddam, M. Srhir, I. A. Takenouti, and H. , Corrosion of copper in 3% NaCl solution polluted by sulphide ions, Corrosion Science, vol.47, pp.3249-3266, 2005.

R. , L. Blengino, J. M. Fiaud, C. Rocha, F. R. Et et al., Morfology and mechanisms of formation of natural patinas on archaeological Cu-Sn alloys, Corrosion Science, vol.4012, pp.2083-2111, 1998.

S. Paulo, Brazil: Part 1. Major inorganic ions in rainwater as evaluated by capillary electrophoresis with contactless conductivity detection, Atmospheric Environment, vol.37, pp.105-115, 2003.

R. , M. Turcu, and F. , High-resolution Kelvin probe microscopy in corrosion science Scanning Kelvin probe force microscopy (SKPFM) versus classical scanning Kelvin probe (SKP), Electrochimica Acta, vol.53, pp.290-299, 2007.

R. , B. M. Vera-r, and J. P. Hidalgo, Characterisation and properties of synthetic patina on copper base sculptural alloys, Corrosion Science, vol.52, issue.10, pp.3212-3224, 2010.

R. , S. Fedel, M. Deflorian, F. Vadillo, and M. C. , Localized electrochemical techniques: theory and practical examples in corrosion studies, C. R. Chim, vol.11, pp.984-994, 2008.

S. , M. Alonso, M. C. Perrot, H. Rose, D. Vivier et al., Etude de la corrosion du cuivre par microélectrochimie : comparaison entre microélectrode et microcellule, IN : In: FORUM SUR LES IMPEDANCES ELECTROCHIMIQUES, 22éme, pp.161-172, 2010.

S. M. , G. J. , P. H. , and R. D. Vivier-v, Microelectrochemistry of copper in NaCl solution: Comparison between conventional microelectrode and microelectrochemical cell, Electrochemistry Communications, vol.12, issue.9, pp.1230-1232, 2010.

S. , J. Odnevall, W. Leygraf, C. Le-bozec, and N. , Corrosioninduced copper runoff from naturally and pre-patinated copper in a marine environment, Corrosion Science, issue.48, pp.12-4316, 2006.

S. , S. Sahre, M. Kautek, and W. , In-situ grazing incidence X-ray diffractometry observation of pitting corrosion of copper in chloride solutions, Corrosion Science, vol.41, issue.10, pp.1899-1909, 1999.

S. , G. M. Birbilis, and N. G. Buchheit-;-r, Corrosion of Aluminum and its Alloys Shreir's Corrosion, 1974.

S. , F. Meyer, and B. , Voltammetry of solid microparticles immobilized on electrode surfaces Electroanalytical chemistry: a series of advances, p.20, 1998.

S. , J. W. Lohrengel, and M. M. Stability, reactivity and breakdown of passive films. Problems of recent and future research, Electrochimica Acta, vol.45, pp.15-16, 2000.

S. , J. W. Tsakova, and V. , Electrochemical microsystem technologies: from fundamental research to technical systems, Electrochimica Acta, vol.44, pp.3605-3627, 1999.

G. , S. Souto, and R. M. , Use of SVET and SECM to study the galvanic corrosion of an iron?zinc cell, Corrosion Science, vol.49, pp.726-739, 2007.

S. , A. M. Battocchi, D. Tallman, and D. E. Bierwagen, SVET and SECM imaging of cathodic protection of aluminium by a Mg-rich coating, Corrosion Science, vol.49, pp.3838-3849, 2007.

S. , H. Jung, Y. Lee, K. Dao, and L. H. , Electrochmical impedance spectroscopy of porous electrodes: effect of pore size distribution

A. Srivastava and R. Balasubramaniam, Electrochemical impedance spectroscopy study of surface films formed on copper in aqueous environments, Materials and Corrosion, vol.24, issue.9, 2005.
DOI : 10.1002/maco.200503866

S. , D. Khaselev, O. Auinat, M. Ein-eli, and Y. , Initiation of copper dissolution in sodium chloride electrolytes, Electrochimica Acta, vol.51, pp.5660-5668, 2006.

S. , H. Johansson, and L. , The formation of black patina on copper in humid air containing craces of SO2, Journal of the Electrochemical Society, vol.144, issue.1, pp.81-89, 1997.

S. , T. Böhni, and H. , Microelectrodes for corrosion studies in Microsystems

T. , J. G. Tiller, and A. K. , Formation and breakdown of surface films on copper in sodiumhydrogen carbonate and sodium chloride solutions. I. Effects of anion concentrations, Br. Corros. J. n, vol.7, pp.256-262, 1972.

T. , J. Graedel, and T. E. , Model studies of aqueous chemistry. IV. Initial (NH4)2SO4-induced atmospheric corrosion of copper, Journal of the Electrochemical Society, vol.144, issue.8, pp.2666-2675, 1997.

T. , J. E. Leygraf, and C. , Atmospheric corrosion of SO 2 and NO 2 ? A comparison of laboratory and field-exposed copper

T. , B. V. Perkins, R. S. Kozlowska, H. Conway, and B. , Impedance and formation characteristics of electrolytically generated silver oxides?I formation and reduction of surface oxides and the role of dissolution processes, Electrochimica Acta, vol.17, pp.1447-1469, 1972.

T. , B. Keddam, M. Takenouti, H. Srhiri, and A. , Protective effect of electropolymerized 3-amino 1,2,4-triazole towards corrosion of copper in 0.5 M NaCl, Corrosion Science, pp.44-997, 2002.

T. , D. Silva, and J. C. , Anodic behavior of copper in chloride/tolytriazole and chloride/benzotriazole solutions, Corrosion, vol.53, issue.1, pp.16-25, 1997.

T. , D. Sun, and R. H. , Intergranular/transgranular fatigue of copper: Influence of environment on crack path and propagation rates, Materials Science and Engineering A, vol.219, pp.1-256, 1996.

Y. I. Tur-'yan, Microcells for voltammetry and stripping voltammetry Talanta, pp.1-13, 1997.

U. , M. Kokubo-m, . Mohamedi-m, and . Uchida-i, Porous-microeletrode study on Pt/C catalysts for methanol electrooxidation, Electrochimica Acta, vol.48, pp.1367-1374, 2003.

M. , J. M. Edwards, and H. G. , Comparative study of mobile Raman instrumentation for art analysis, Analytica Chimica Acta, vol.588, issue.1, pp.108-116, 2007.

J. Vazquez-arenas, Experimental and modeling analysis of the formation of cuprous intermediate species formed during the copper deposition on a rotating disk electrode, Electrochimica Acta, vol.55, issue.10, pp.3550-3559, 2010.
DOI : 10.1016/j.electacta.2010.01.050

V. , R. Delgado, D. Rosales, and B. M. , Effect of unusually elevated SO2 atmospheric content on the corrosion of high power electrical conductors ? Part

V. , V. Krawiec, H. Heintz, O. Oltra, and R. , The use of local electrochemical probes and surface analysis methods to study the electrochemical behaviour and pitting corrosion of stainless steels, Electrochimica Acta, vol.52, pp.15-4994, 2007.

V. , J. R. Varela, F. E. Codaro, E. N. Rosales, B. M. Moriena et al., A survey of argentinean atmospheric corrosion: II? Copper samples, Corrosion Science, vol.39, issue.4, pp.655-679, 1997.

V. Vivier, . Sur, and . Impedances-electrochimiques, Récents développements em spectroscopie d'impedance électrochimique locale IN : In: FORUM, pp.5-18, 2010.

V. Vivier, Microélectrode à cavité. Principe, développement et applications pour l'étude de la réactivité de matériaux insolubles. Saint-Étienne : Publications de l, 2009.

V. Vivier, Étude de matériaux en poudre au moyen de la microélectrode à cavité, 2000.

N. , J. Fedoroff, M. Michel, D. Yu, and L. , Electrochemical study of Bi 2 O 3 e Bi 2 O 3 CO3 by means of a cavity microelectrode. I. observed phenomena and direct analysis of results, Journal Electrochemical Society, vol.11, pp.147-4252, 2000.

V. , C. Cha, C. S. Nadelec, J. Yu, and L. , Cavity microeletrode for studying battery materials: application to polyaniline powder, Electrochemistry Communications, vol.2, issue.3, pp.180-185, 2000.

A. Vogel and J. W. Schutze, A new microcell for electrochemical surface analysis and reactions, Electrochimica Acta, vol.44, issue.21-22, pp.21-223751, 1999.
DOI : 10.1016/S0013-4686(99)00080-8

W. , I. O. Leygraf, and C. , Seasonal variations in corrosion rate and runoff rate of copper roofs in an urban and a rural atmospheric environment, Corrosion Science, vol.43, issue.12, pp.2379-2396, 2001.

W. M. Toyoda-e, . Handa-t, . Ichino-t, . Kuwaki-n, . Higashi-y et al., Evolution of patinas on copper exposed in a suburban area

W. M. and Y. H. Tanaka-t, Differences between corrosion products formed on copper exposed in Tokyo in summer and winter, Corrosion Science, vol.45, issue.7, pp.1439-1453, 2003.

Y. , M. Nagano, M. Oriani, and R. A. , Dependence of corrosion potential and corrosion rate of a low-alloy steel upon depth of aqueous solution, Corrosion Science, vol.40, pp.1447-1453, 1998.

Z. , A. G. Pirogov, B. Y. Yurjev, and O. A. , Open circuit potential transients and electrochemical quartz crystal microgravimetry measurements of dissolution of copper in acidic sulfate solutions, Corrosion Science, vol.46, pp.1083-1093, 2004.

Z. , X. He, W. Wallinder, I. O. Pan, J. Leygraf et al., Determination of instantaneous corrosion rates and runoff rates of copper from naturally patinated copper during continuous rain events, Corrosion Science, vol.44, issue.9, pp.2131-2151, 2002.

Z. , Y. N. Zi, J. L. Zheng, M. S. Zhu, and J. W. , Corrosion behavior of copper with minor alloying addition in chloride solution, Journal of Alloys and Compounds, vol.462, pp.240-243, 2008.

Z. , F. Thierry, and D. , Localized electrochemical impedance spectroscopy for studying the degradation of organic coatings, Electrochimica Acta, vol.42, pp.3293-3301, 1997.

Z. , F. Grassi, V. Frignani, A. Trabanelli, and G. , Inhibition of copper corrosion by silane coatings, Corrosion Science FONTES CONSULTADAS Internet, issue.46, pp.2853-2865, 2004.

. Notas-de-aula, QFL-5625-1 -Espectroscopia de Superfícies, p.2201, 2008.