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. Bi, Bi(2)-I(3)#2 3.0405(5) Bi(2)-I(3) 3.0405(6) Bi(2)-I(3)#3 3.0405(6) Bi(2)-I(3)#4 3.0405(5) Bi(2)-I(1) 3.4283(18) Cl(1)-Bi(1) 2.6821(10) I(1)-Bi(1) 2.9340(12) I(2)-Bi(1)#5 3, )-Cl(1)#3 2.6820(10) Bi(1)-Cl(1)#4 2.6821(10) Bi(1)-Cl(1)#2 2.6820(10) Bi(1)-I(2)#6 3, p.972631613161

. Sb, Sb(1)-Cl(1) 2 Sb(1)-Cl(4) 2.6071(14) Sb(1)-Cl(3) 2.6528(15) Cl(2A)-Cl(2B) 1, Cl(2B)#1 2.194(6) Sb(1)-Cl(2A) 2.3589(10) Sb(1)-Cl(5) 2.603) N(2)-C(1) 1.333(7) N(2)-N(1) 1.384(7) N(1)-H(4) 0) N(3)-C(10) 1.335(7) C(3)-C(4) 1.378(7) C(3)-C(2))-C(9) 1.404(7) C(9)-C(10) 1.350(9) C(9)-H(1) 0) C(7)-H(12) 0.98(4) C(4)-H(9) 0, pp.75-80

. Bi, C(6)-N(1)-C(1) 120, ) N(1)-C(1)-H(1A)

. Bi, C(6)-N(1)-C(1) 121, ) N(1)-C(1)-H(1A)

. Bi, 7066(17) Bi(2)-Cl(7) 2.7198(18) Bi(2)-Cl(5)#1 2 Bi(3)-Cl(7) 2.9704(18) Cl(1)-Bi(1) 2.5185(18) Cl(2)-Bi(1) 2.5292(17) Cl(3)-Bi(1) 2, Cl(8) 2.5627(17) Bi(2)-Cl(6) 2.5811(16) Bi(2)-Cl(4)#1 2Cl(5) 2.8636(15) Bi(3)-Cl(10) 2.5079(18) Bi(3)-Cl(11) 2.6009(18) Bi(3)-Cl(9) 2.7204(18) Bi(3)-Cl(12) 2.7852(18) Bi(3)-Cl(13) 2.8713) Cl(4)-Bi(2)#1 2.7066(17) Cl(4)-Bi(1) 2.9975(17) Cl(5)-Bi(2)#1 2.8628(15) Cl(12)-Bi(1) 2.9283(17) Cl(13)-Bi(1) 2.9709) C(1)-H(1A) 0, pp.86285575337-9

. Bi, #1-Cl(4)-Bi(1) 172

. Bi, #1-Cl(5)-Bi(2) 95

. Sb, Cl(1)-Sb(1)-Cl(3) 90 Cl(1)-Sb(1)-Cl(2) 90 Cl(3)-Sb(1)-Cl(2) 91 Cl(1)-Sb(1)-Cl(4) 86)-Sb(1)-Cl(4)#2 85, ) Cl(3)-Sb(1)-Cl(4) 90.29(4) Cl(2)-Sb(1)-Cl) Cl(3)-Sb(1)-Cl(4)#2 175.03(4) Cl(2)-Sb(1)-Cl(4)#2 91) Cl(4)-Sb(1)-Cl(4)#2 86) _____________________________________________________________ Symmetry transformations used to generate equivalent atoms, pp.1-3

. Bi, Cl(4)-Bi(1)-Cl(2) 95.03(9) Cl(4)-Bi(1)-Cl(3) 89 Cl(2)-Bi(1)-Cl(3) 87 Cl(4)-Bi(1)-Cl(5) 86 Cl(4)-Bi(1)-Cl(1) 91, )#1 98) Cl(3)-Bi(1)-Cl(5)) Cl(3)-Bi(1)-Cl(1) 92.32(8) Cl(5)-Bi(1)-Cl(1) 92.08(7) Cl(4)-Bi(1)-Cl(1)#1 172

. Bi, Bi(1)#1 100

. Bi, Cl(5)-Bi(1)-Cl(1) 90 Cl(5)-Bi(1)-Cl(4) 91.91(7) Cl(1)-Bi(1)-Cl(4) 89.02(8) Cl(5)-Bi(1)-Cl(2) 90, )-Bi(1)-Cl(2) 89.12(9) Cl(4)-Bi(1)-Cl) Cl(5)-Bi(1)-Cl(3)#1 91.39(9) Cl(1)-Bi(1)-Cl(3)#1 178.38(10) Cl(4)-Bi(1)-Cl(3)#1 90, pp.1-38

. Bi, Br(4)-Bi(1)-Br(2) 96 Br(4)-Bi(1)-Br(3) 89 Br(2)-Bi(1)-Br(3) 88 Br(2)-Bi(1)-Br(5) 89 Br(3)-Bi(1)-Br(5) 176.02(3) Br(4)-Bi(1)-Br(1) 89, ) Br(5)-Bi(1)-Br(1) 92, pp.173-91

. Bi, #1-Cl(5)-Bi(2) 95

. Bi, Bi(1)-Cl(12) 2.927(3) Bi(1)-Cl(13) 2 Bi(1)-Cl(4) 3 Bi(3)-Cl(7)#1 2 Bi(3)-I(1) 3.071(11) Cl(4)-Bi(2) 2, ) Bi(3)-Cl(10) 2.509(3) Bi(3)-Cl(11) 2.601(3) Bi(3)-Cl(9) 2.679(10) Bi(3)-Cl(12) 2.766(2) Bi(3)-Cl(13) 2.868) Cl(5)-Bi(2)#1 2.856(2) Cl(5)-Bi(2) 2.858(2) Cl(6)-Bi(2) 2.578(2) Cl(7)-Bi(2) 2.723(2) Cl(7)-Bi(3)#1 2.957(2) Cl(8)-Bi) N(4)-C(22) 1.497(13) C(1)-H(1A) 0, pp.337-349

. Bi, #1-Cl(5)-Bi(2) 95

. Bi, Cl(7)-Bi(3)#1 176