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            <title xml:lang="en">Relationship between the structure and the physical properties of polymers based on furandicarboxylic acid obtained from biomass</title>
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            <idno type="halRefHtml">Materials Science [cond-mat.mtrl-sci]. Normandie Université; Esposito, 2020. English. &lt;a target="_blank" href="https://www.theses.fr/2020NORMR113"&gt;&amp;#x27E8;NNT : 2020NORMR113&amp;#x27E9;&lt;/a&gt;</idno>
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            <idno type="stamp" n="INSA-ROUEN">Institut National des Sciences Appliquées de Rouen</idno>
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            <idno type="stamp" n="COMUE-NORMANDIE">Normandie Université</idno>
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                <title xml:lang="en">Relationship between the structure and the physical properties of polymers based on furandicarboxylic acid obtained from biomass</title>
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                <authority type="supervisor">Éric Dargent</authority>
                <authority type="supervisor">Antonella Esposito</authority>
                <authority type="jury">Alice Mija [Rapporteur]</authority>
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                <term xml:lang="en">Crystallization kinetics</term>
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                <term xml:lang="en">Copolyesters</term>
                <term xml:lang="en">Glass transition</term>
                <term xml:lang="en">Molecular dynamics</term>
                <term xml:lang="fr">Copolyesters</term>
                <term xml:lang="fr">Transition vitreuse</term>
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                <term xml:lang="fr">Cinétiques de cristallisation</term>
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              <p>This work explored for the first time some physical properties of a new generation of copolyesters obtained from physical mixtures of two isomers: 2,5-furandicarboxylic acid (2,5-FDCA) and 2,4-furandicarboxylic acid (2,4-FDCA). The 2,5-FDCA isomer is the most studied today because it is used to obtain Poly (Ethylene-2,5-Furanoate) (2,5-PEF), which is the best bio-based candidate to replace the giant of the plastic industry, Poly (Ethylene-Terephthalate) (PET). The 2,4-FDCA isomer has also been studied because it can be used to obtain Poly (Ethylene-2,4-Furanoate) (2,4-PEF), with an extremely slow kinetics of crystallization. It has been shown that the combination of these two isomers allows to obtain copolymers with adjusted and controlled properties. The dynamics of molecular relaxation in the amorphous phase, both localized and cooperative, have been studied over a wide range of frequencies and temperatures, according to approaches typically used to study glass-forming liquids. Then, the investigation was directed towards the influence of the position of the carbonyl group on the furan ring on the ability to crystallize and the kinetics of crystallization. Several experimental techniques have been used: differential scanning calorimetry (DSC), modulate-temperature differential scanning calorimetry (MT-DSC), dielectric relaxation spectroscopy (DRS) and measurement of thermos-stimulated depolarization currents (TSDC).</p>
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              <p>L'objectif de ce travail est d'explorer pour la première fois certaines propriétés physiques d'une nouvelle génération de copolyesters obtenus à partir d'un mélange physique de deux isomères : l’acide-2,5-furandicarboxylique (2,5-FDCA) et l’acide-2,4-furandicarboxylique (2,4-FDCA). L’isomère 2,5-FDCA est aujourd’hui le plus étudié, car il est utilisé pour obtenir le Poly(Ethylène-2,5-Furanoate) (2,5-PEF), qui est le meilleur candidat biosourcé pour remplacer le géant de l'industrie plastique, le Poly (Ethylène-Téréphtalate) (PET). Son isomère, le 2,4-FDCA, a aussi été étudié puisqu’il permet d’obtenir le Poly (Ethylène-2,4-Furanoate) (2,4-PEF), qui possède une cinétique de cristallisation extrêmement lente. Il a été montré que la combinaison de ces deux isomères permet d’obtenir des copolymères ayant des propriétés ajustées et contrôlées. Les dynamiques de relaxation moléculaire dans la phase amorphe, aussi bien localisées que coopératives, ont été étudiées dans une large gamme de fréquences et températures, selon les approches caractéristiques de l’étude des liquides formateurs de verre. Ensuite, l’étude a été orientée vers l'influence de la position du groupe carbonyle sur le furane sur l’aptitude à cristalliser et les cinétiques de cristallisation. Plusieurs techniques expérimentales ont été utilisées : calorimétrie différentielle à balayage (DSC), calorimétrie différentielle à balayage avec modulation de température (MT-DSC), spectroscopie de relaxation diélectrique (DRS) et mesure des courants de dépolarisation thermostimulés (TSDC).</p>
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