High-temperature PEM Fuel Cell Characterization: an Experimental Study Focused on Potential Degradation due to the Polarization Curve - Institut National de l'Energie Solaire
Communication Dans Un Congrès Année : 2022

High-temperature PEM Fuel Cell Characterization: an Experimental Study Focused on Potential Degradation due to the Polarization Curve

Résumé

High-Temperature Proton Exchange Membrane Fuel Cell constant current ageing tests highlighted that the characterizations used to monitor the state of health of single cells could be potentially degrading. An experimental campaign to analyze potential degradation due to polarization curves was carried out. More exactly, four methodologies to generate a polarization curve including Electrochemical Impedance Spectroscopies (EIS) were cycled 30 times. The tested single cells were based on a commercial PBI Membrane Electrodes Assembly (MEA) with an active surface of 45 cm 2 (BASF Celtec®-P 1100 type). Before the first cycling test and after the last cycling one, complete characterizations, composed by a voltammetry and a polarization curve including EIS, were performed. The results show that one of the MEA has a voltage which increased for one of the four methods to obtain the polarization curve. This growth is linked to a decrease of ohmic losses: in an unexpected way, it could be considered as a way to improve the break-in period. Similarly, the monitoring of CO 2 emission (as corrosion has been suspected to be involved at high voltage, i.e. low current density) confirms the potential degradation of the electrodes during the measurement of the polarization curve.
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Dates et versions

hal-04848355 , version 1 (19-12-2024)

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Mathieu Baudy, Amine Jaafar, Sylvain Rigal, Christophe Turpin, Sofyane Abbou. High-temperature PEM Fuel Cell Characterization: an Experimental Study Focused on Potential Degradation due to the Polarization Curve. European Fuel Cells and Hydrogen Piero Lunghi Conference (EFC21), Dec 2021, Online (covid), Italy. pp.04017, ⟨10.1051/e3sconf/202233404017⟩. ⟨hal-04848355⟩
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